The correct option is
D Add a catalyst
∙ Lowering the temperature will decrease the value of the rate constant.
⇒ rate of reaction will decrease.
∙ Adding a catalyst will increase the rate of the reaction.
⇒ rate of reaction will increase.
∙ Decreasing pressure will indirectly affect the rate of reaction as concentration would decrease.
⇒ rate of reaction will decrease.
∙ Using larger pieces of solid reactants will decrease the number of collisions and hence affect rate.
⇒ rate of reaction will decrease.
∙ Decreasing the concentration of reactants will decrease the rate.
⇒ rate of reaction will decrease.
Hence, adding a catalyst is the best one out of given options.