Which compound among the following has the highest oxidation number of P? PH3,H3PO2,PCl3 and H3PO4.
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Solution
H3PO4 has the highest oxidation number of P. Let X be has the oxidation number of P in H3PO4. 3(+1)+X+4(−2)=0 3+X−8=0 X=+5 The oxidation number of P in H3PO4 is +5. The oxidation number of P in PH3,H3PO2,PCl3 is −3, +1 and +3 respectively.