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Question

Which compound amongst the following has the highest oxidation number of Mn?

A
KMnO4
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B
K2MnO4
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C
MnO2
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D
Mn2O3
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Solution

The correct option is A KMnO4
Let the oxidation number of Mn be x.
Oxidation state of K=+1, O=2.
(A) KMnO4: 1+x+4×(2)=0
x=+7
(B) K2MnO4: 2×1+x+4×(2)=0
x=+6
(C)MnO2: x+2×(2)=0
x=+4
(D) Mn2O3: 2x+3×(2)=0
x=+3
therefore highest oxidation number of Mn is +7 in KMnO4

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