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Question

Which describes the final laboratory observation when 0.40 moles of NaOH(s) is added to 0.50 liters of 0.60 M CuCl2 solution?

A
A precipitate forms; excess copper ions are found.
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B
A precipitate forms; excess hydroxide ions are found.
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C
A nearly colorless solution forms; excess copper ions are found.
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D
A nearly colorless solution forms; excess hydroxide ions are found.
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Solution

The correct option is B A precipitate forms; excess copper ions are found.
Balanced reaction is:
2NaOH0.4moles+CuCl20.3moles2NaCl+Cu(OH)2ppt
x= No. of moles = Molarity × Volume =0.5×0.6=0.3
1 mole of CuCl2 react with 2 moles of NaOH
0.4 mole of NaOH react with 0.2 moles of CuCl2
0.1 mole of CuCl2 will be left.
So, percipitate is formed (Cu(OH)2) and excess copper ions are left.

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