Which does not involve a carbocation?

(C H_{3})_{3} C C l + A g N O_{3} \to

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(C H_{3})_{3} C O H + H C l \to

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(C H_{3})_{3} C H + C l_{2} + h v \to

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C H_{3} C H = C H C H_{2} O H + H_{3} O^{+} \to

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Solution

The correct option is C $(C H_{3})_{3} C H + C l_{2} + h v \to$
In presence of sunlight, the chlorine molecule undergoes homolytic fission to form chlorine free radical. It reacts with $(C H_{3})_{3} C H$ to form $(C H_{3})_{3} C \cdot$ free radical. Thus the reaction proceeds by free radical mechanism.
Thus the carbocation is not involved in the mechanism for the reaction $(C H_{3})_{3} C H + C l_{2} + h v \to$ .

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