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Question

Which expression gives the correct value for the standard potential for a gold-rhodium voltaic cell?

Half-reactionE(V)
Rh+3(aq)+3eRh(s)0.76 V
Au+(aq)+eAu(s)1.69 V

A
1.69 V+0.76 V
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B
1.69 V0.76 V
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C
3(1.69) V+0.76 V
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D
3(1.69) V0.76 V
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Solution

The correct option is A 1.69 V0.76 V
We know that, metal having higher reduction potential undergoes reduction;
so, Au will undergo reduction and Rh will undergo oxidation.
E0cell = 1.69 V - 0.76 V

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