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Nucleophilic Addition at the Carbonyl

Which has the...

Question

Which has the highest pH ? a) CH3COOK b) Na2CO3 c) NH4Cl d) NaNO3

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Q. The order of pH of 0.200 M solutions of

N H_{4} N O_{3}, N a N O_{3}

N a_{2} C O_{3}

Q. Match the column I with column II and mark the appropriate choice.

Column I	Column II
(A) $C H_{3} C O O N a$	(i) Almost neutral, pH > $7$ or < $7$
(B) $N H_{4} C l$	(ii) Acidic, pH < $7$
(C) $N a N O_{3}$	(iii) Alkaline, pH > $7$
(D) $C H_{3} C O O N H_{4}$	(iv) Neutral, pH = $7$

Q. In the above reaction if

A

N H_{4} C l

D

C O_{2}

B

C

respectively are :

+ N a O H \to N a C l + N H_{3} + H_{2} O

N H_{3} + C O_{2} + H_{2} O \to (B)

+ N a C l \to (C) + N H_{4} C l

\to N a_{2} C O_{3} + H_{2} O + (D)

Q. Complete the following reaction:

N a N O_{3} + N H_{4} C l ⟶

Q. For the reaction,

F e (N O_{3})_{3} + N a_{2} C O_{3} \to F e_{2} (C O_{3})_{3} + N a N O_{3}

Initially if 2.5 moles of

F e (N O_{3})_{2}

and 3.6 moles of

N a_{2} C O_{3}

is taken. If 6.3 moles of

N a N O_{3}

is obtained then

%

yield of given reaction will be:

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Nucleophilic Addition at the Carbonyl

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