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Question

Which is not correctly matched?
(1) Basic strength of oxides:
Cs2O<Rb2O<K2O<Na2O<Li2O
(2) Stability of carbonates:
Na2CO3<K2CO3<Rb2CO3<Cs2CO3
(3) Stability of bicarbonates:
LiHCO3<NaHCO3<KHCO3<RbHCO3<CsHCO3
(4) Melting point:
NaF<NaCl<NaBr<NaI

A
1 and 4
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B
1 and 3
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C
1 and 2
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D
2 and 3
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Solution

The correct option is A 1 and 4
The basic nature of oxides increases down the group.
Cs2O>Rb2O>K2O>Na2O>Li2O

Lattice energy 1r++r
So more the L.E., more is the melting point.
NaF>NaCl>NaBr>NaI

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