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Redox Reactions

Which is the ...

Question

Which is the most suitable reagent for the following conversion?
$C H_{3} - C H = C H - C H_{2} - O ∥ C - C H_{3} \to C H_{3} - C H = C H - C H_{2} - O ∥ C - O H$

A

Tollens' reagent

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B

Benzoyl peroxide

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C

I_{2}

and

N a O H

solution followed by hydrolysis

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D

L i A l H_{4} / C_{2} H_{5} O H

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Solution

The correct option is C $I_{2}$ and $N a O H$ solution followed by hydrolysis
a) Ketones are mostly not oxidisable by Tollens' reagent.
b) Benzoyl peroxide can do epoxidation as well as ester formation.
c) $I_{2}$ and $N a O H$ solution oxidises methyl ketone into sodium carboxylate which on further hydrolysis gives carboxylic acid.
d) $L i A l H_{4} / C_{2} H_{5} O H$ will reduce the ketone into alcohol.

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Similar questions

Q. Which is the most suitable reagent for the following conversion?

C H_{3} - C H = C H - C H_{2} - O | | C - C H_{3} \to C H_{3} - C H = C H - C H_{2} - O | | C - O H

Q. Which is the most suitable reagent for the following transformation?

C H_{3} - C H = C H - C H_{2} - O H | C H - C H_{3} ⟶ C H_{3} - C H = C H - C H_{2} - C O O H

Q. Which is the most suitable reagent among the following to distinguish compound (3) from rest of the compounds?
1.

C H_{3} - C \equiv C - C H_{3}

C H_{3} - C H = C H - C H_{3}

C H_{3} - C H_{2} C \equiv C H

C H_{3} - C H = C H_{2}

Q. Write IUPAC names of the following

@CH3-CH2-CH=CH2
@CH3-CH2-CH2-C(CH3)2-CH3
@CH3-CH2-CHO
@CH3-CH(OH)-CH3
@CH3-CH2-CH2-COOH

Q. Which amongst the following is a positional isomer of

{CH}_{3} - {CH}_{2} - CH = {CH}_{3}

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