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Question

Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated HCl at room temperature?

A
CH3CH2CH2OH
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B
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C
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D
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Solution

The correct option is D
At room temperture, alkyl halide which form more stable carbocation intermediate will give stable and more efficient product.

Formation of 3 carbocation as intermediate during reaction does not require any heating, it occurs at room temperature due to its stable intermediate.
Hence, option D is correct.

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