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Standard XII
Chemistry
Molecular Orbital Energy Diagrams
Which of the ...
Question
Which of the following best describes the diagram of a molecular orbital?
A
A bonding
π
orbital
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B
A non-bonding orbital
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C
An antibonding
σ
orbital
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D
An antibonding
π
orbital
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Solution
The correct option is
D
An antibonding
π
orbital
An antibonding
π
orbital best describes the diagram of a molecular orbital.
Two p orbitals laterally overlap to form pi bond.
Out of phase combination of these two p orbitals give
π
∗
MO.
Hence, the correct option is D.
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Similar questions
Q.
Which is correct statement about
σ
−
and
π
−
molecular orbitals? Statements are
(i)
π
−
bonding orbitals are ungerade
(ii)
π
−
antibonding orbitals are ungerade
(iii)
σ
−
antibonding orbitals are gerade
Q.
Explain the terms
(i) bonding molecular orbitals,
(ii) antibonding molecular orbitals,
(iii) non-bonding molecular orbitals.
Q.
According to MOT, two atomic orbitals overlap resulting in the formation of molecular orbitals. Number of atomic orbitals overlapping together is equal to the molecular orbital formed. The two atomic orbital thus formed by LCAO (linear combination of atomic orbital) in the same phase or in the different phase are known as bonding and antibonding molecular orbitals respectively. The energy of bonding molecular orbital is lower than that of the pure atomic orbital by an amount
Δ
. This known as the stabilization energy. The energy of antibonding molecular orbital is increased by
Δ
′
(destabilization energy).
How many nodal plane(s) is/are present
σ
(s and p)
in bonding molecular orbital?
Q.
During the formation of
O
−
2
from
O
2
(1) Electron is added to the
π
antibonding orbital.
(2) Bond length increases.
(3) Bond order decreases.
Correct option among the following is:
Q.
Assertion : Fluorine molecule has bond order one.
Reason : The number of electrons in the antibonding molecular orbitals is two less than that in bonding molecular orbitals.
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