Which of the following can be obtained in carbylamine reaction?

C_{6} H_{5} N H_{2}

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C O C l_{2}

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C_{6} H_{5} C N

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C_{6} H_{5} N C

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Solution

The correct option is D $C_{6} H_{5} N C$

Carbylamine reaction is used for test of primary amines. In this reaction primary amines react with an alcoholic solution of potassium hydroxide and trichlormethane (or chloroform) to forms foul smelling isocyanide.
$C_{6} H_{5} N H_{2} + 3 K O H + C H C l_{3} \to C_{6} H_{5} N C + 3 K C l + 3 H_{2} O$
Hence, (d) is the correct option.

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