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Coordination Isomerism

Which of the ...

Question

Which of the following can show coordination isomerism?

A

[C u (N H_{3})_{4}] [P t C l_{4}]

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B

[F e (N H_{3})_{6}]_{2} [P t (C N)_{6}]_{3}

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C

[C o (N H_{3})_{6}] [C r (C_{2} O_{4})_{3}]

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D

[P t (e n)_{3}] (S O_{4})_{2}

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Solution

The correct options are
A $[C u (N H_{3})_{4}] [P t C l_{4}]$
C $[C o (N H_{3})_{6}] [C r (C_{2} O_{4})_{3}]$
$[C u (N H_{3})_{4}] [P t C l_{4}]$ can show coordination isomerism because $N H_{3}$ and $C l$ can interchange the coordination sphere. Also, $[C o (N H_{3})_{6}] [C r (C_{2} O_{4})_{3}]$ can show coordination isomerism as $N H_{3}$ and $C_{2} O_{4}$ can interchange the coordination sphere.

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Similar questions

Q. Which of the following can show coordination isomerism?
(i)

[C u {({N H}_{3})}_{4}] [P t {C l}_{4}]

{[F e {({N H}_{3})}_{6}]}_{2} {[P t {(C N)}_{6}]}_{3}

[C o {({N H}_{3})}_{6}] [C r {(C_{2} O_{4})}_{3}]

[P t {(e n)}_{3}] {({S O}_{4})}_{2}

Q. The total possible coordination isomers for the following compounds respectively are:

[C o (e n)_{3}] [C r (C_{2} O_{4})_{3}]

[C u (N H_{3})_{4}] [C u C l_{4}]

[N i (e n)_{3}] [C o (N O_{2})_{6}]

.

Q. Which one of the following pairs of isomers and types of isomerism are correctly matched?
(i)

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

[C u (N H_{3})_{4}] [P t C l_{4}]

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

Select the correct answer using the codes given below:

Q. The total number of possible isomer for the complex compound :

[C u (N H_{3})_{4}] [P t C l_{4}]

Q. Name the types of isomerism shown by the following pairs of compounds:
(i)

[C u {(N H_{3})}_{4}] [P t {C l}_{4}]

[P t {(N H_{3})}_{4}] [C u {C l}_{4}]

{[C o {(P n)}_{2} {C l}_{2}]}^{+}

{[C o {(t n)}_{2} {C l}_{2}]}^{+}

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