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Question

Which of the following complex compounds will not exhibit geometrical isomerism?

A
[Co(NH3)4(H2O)Cl]SO4
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B
[Co(NH3)3Cl3]
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C
K2[PtBr2Cl2]
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D
K2[NiBr2Cl2]
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Solution

The correct option is D K2[NiBr2Cl2]
[Co(NH3)4(H2O)Cl]SO4 and [Co(NH3)3Cl3] have octahedral geometry and K2[PtBr2Cl2] has square planar geometry. So, all of them can show geometrical isomerism. But, K2[NiBr2Cl2] has a tetrahedral geometry which cannot show geometrical isomerism.

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