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Types of Complexes Based on Ligands

Which of the ...

Question

Which of the following complexes are heteroleptic?

[C r (N H_{3})_{6}]^{3 +}

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[F e (N H_{3})_{4} C l_{2}]^{+}

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[M n (C N)_{6}]^{4 -}

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[C o (N H_{3})_{4} C l_{2}]^{+}

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Solution

The correct options are
B $[F e (N H_{3})_{4} C l_{2}]^{+}$
D $[C o (N H_{3})_{4} C l_{2}]^{+}$
Homoleptic complexes are compounds which contain identical ligands whereas the heteroleptic complexes contain more than one type of the ligand.

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Similar questions

Which of the following complexes are heteroleptic?
(a) $[C r (N H_{3})_{6}]^{3 +}$
(b) $[F e (N H_{3})_{4} C l_{2}]^{+}$
(c) $[M n (C N)_{6}]^{4 -}$
(d) $[C o (N H_{3})_{4} C l_{2}]$

Q. The magnetic moments of complexes given below are in the order:

(I)

[N i (C O)_{4}]

(II)

[M n (C N)_{6}]^{4 -}

(III)

[C r (N H_{3})_{6}]^{3 +}

(IV)

[C o F_{6}]^{3 -}

Q. Which of the following complexes are low spin and diamagnetic?
(a)

K_{4} (O s (C N)_{6}]

(b)

[M o (C O)_{6}]

(c)

[M n (C N)_{6}]^{4 -}

Select the correct answer using the codes given below:

Q. The following complexes are given:
(1)

t r a n s - [C o (N H_{3})_{4} C l_{2}]^{+}

(2)

c i s - [C o (N H_{3})_{2} (e n)_{2}]^{3 +}

(3)

t r a n s - [C o (N H_{3})_{2} (e n)_{2}]^{3 +}

(4)

N i C l_{4}^{2 -}

(5)

T i F_{6}^{2 -}

(6)

C o F_{6}^{3 -}

Choose the correct code:

Q. The complex

{[M n {(C N)}_{6}]}^{4 -}

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Which of the following complexes are heteroleptic?

The correct options are B [Fe(NH3)4Cl2]+ D [Co(NH3)4Cl2]+Homoleptic complexes are compounds which contain identical ligands whereas the heteroleptic complexes contain more than one type of the ligand.

The correct options are
B $[F e (N H_{3})_{4} C l_{2}]^{+}$
D $[C o (N H_{3})_{4} C l_{2}]^{+}$
Homoleptic complexes are compounds which contain identical ligands whereas the heteroleptic complexes contain more than one type of the ligand.