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Reduction of Amides,Oximes and Azides with LAH

Which of the ...

Question

Which of the following compounds gives p-nitroso derivative on treatment with $N a {N O}_{2} / H C l$ at $273 K$ ?

o-Methyl aniline

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Aniline

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Benzyl amine

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N,N- Dimethyl aniline

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Solution

The correct option is D N,N- Dimethyl aniline
tertiary aryl amines undergo nitrosation in aromatic ring and form p-nitrosoamine.

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Similar questions

The positive carbylamines test is given by
(i) N, N-dimethyl aniline (ii) 2, 4-dimethyl aniline

(iii) N-methyl-O-methyl aniline (iv) p-methyl benzylamine

N a N O_{2} / H C l

0^{o} C

β

N a N O_{2} / H C l

0^{o} C

β

{N a N O}_{2} / H C l

0^{o} C

β

{N a N O}_{2} / H C l

0^{o} C

β

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