Which of the following compounds has the highest bond angle?
A
NH3
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B
H2O
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C
CH4
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D
All are same
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Solution
The correct option is CCH4 NH3 and H2O and CH4 have 1, 2 and zero lone pairs respectively with the hybridization of sp3 and tetrahedral geometry. But the shapes of the three molecules respectively are pyramidal, bent and tetrahedral.
So, in NH3 and H2O, the bond angles are less than 109∘28′ due to LP-BP and LP-LP repulsions respectively.
The bond angle in CH4 is 109∘28′ as it is a regular tetrahedron.