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Question

Which of the following compounds will exhibit cis-trans isomerism?

A
2-butene
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B
2-butyne
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C
2-butanol
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D
butanal
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Solution

The correct option is A 2-butene
The compounds with each doubly bonded carbon attached to two different groups (like Cab=Cab, Cab=Ccd) exhibit geometrical isomerism i.e., cis and trans forms. The geometrical isomerism arises due to the restricted rotation of the double bond.

However, even though there is restricted rotation for a triple bond, alkynes do not exhibit geometrical isomerism, since the triply bonded carbons are attached to only one group each.

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