Which of the following compounds would not give ppt. with $A g N O_{3}$

C H_{3} C H = C H C l

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C H_{2} = C H - C H_{2} C l

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(C H_{3})_{3} C C l

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Solution

The correct option is A $C H_{3} C H = C H C l$
Stable carbocations are produced from (b), (c), (d) but not from (a) as Chlorine is bonded to $s p^{2}$ hybridized carbon and is a vinylic type of carbon.

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