Which of the following conditions will apply conversion of ice into water? ΔHΔSΔG
A
negative negative negative at low T
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B
negative negative positive at low T
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C
positive positive positive at low T
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D
positive positive negative at low T
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Solution
The correct option is B positive positive positive at low T
ΔG=ΔH−TΔS
Melting of ice is an endothermic process as ice absorbs heat from the surroundings to convert into the water. So, ΔH=positive. The randomness of the system increases as solid (ice) changes into liquid (water), therefore, ΔS= positive. At low temperature, ΔH−TΔS is positive. So, ΔG= positive at low T.