Which of the following diazonium salt is relatively stable at $0 - {5^{0}} C$ ?

{C H}_{3} - N \equiv N}^{\oplus} C l^{-}

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{({C H}_{3})}_{2} C H - N \equiv N}^{\oplus} {C l}^{-}

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C_{6} H_{5} - N \equiv N}^{\oplus} {C l}^{-}

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{({C H}_{3})}_{3} C - N \equiv N}^{\oplus} {C l}^{-}

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Solution

The correct option is D ${({C H}_{3})}_{3} C - N \equiv N}^{\oplus} {C l}^{-}$
The $+ I$ effect which stabilizes the $N^{+}$ ion is in the following order $C_{6} H_{5} - < {C H}_{3} - < {({C H}_{3})}_{2} - < {({C H}_{3})}_{3}$
$∴$ The ${{({C H}_{3})}_{3} C - N \equiv N}^{+} {C l}^{-}$ is most stable

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Which of the following diazonium salt is relatively stable at $0 - {5^{0}} C$ ?