Which of the following diazonium salt is relatively stable of $0 - 5^{\circ} C$ - :

C H_{3} C H_{2} N \equiv N}^{\oplus} C l^{-}

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C H_{3} - C (C H_{3})_{2} - N \equiv N}^{\oplus} C l^{-}

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C H_{3} - N \equiv N}^{\oplus} C l^{-}

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(C H_{3})_{3} C - N \equiv N}^{\oplus} C l^{-}

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Solution

The correct option is C $C H_{3} - N \equiv N}^{\oplus} C l^{-}$
The diazonium salt $C H_{3} - N \equiv N}^{\oplus} C l^{-}$ obtained by treatment of methylamine with nitrous acid is relatively stable at $0 - 5^{\circ} C$ .

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