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Question

Which of the following fluorides of xenon is impossible?

A
XeF2
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B
XeF3
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C
XeF4
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D
XeF6
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Solution

The correct option is C XeF3
Xenon is an inert gas. Its electronic configuration is [Kr]4d105s25p6.
All orbitals that are filled have paired electrons.

When one, two or three electrons are promoted from 5p (filled) to 5d (empty) orbitals, two, four and six half-filled orbitals are formed.

Xenon can combine with even number of F atoms to form XeF2, XeF4 or XeF6. It cannot combine with odd number of F atoms.

Thus, formation of XeF3 and XeF5 is not possible.

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