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Question

Which of the following gas is not liberated by the electrolysis of dipotassium succinate solution?

A
Ethene
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B
Ethyne
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C
CO2
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D
H2
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Solution

The correct option is B Ethyne
During the electrolysis of potassium succinate, the anion produced is succinate anion. It gives one ethene molecule and 2 CO2 gas. The reaction is as follows:

(CH2COO)2CH2=CH2+2CO2(g)+2e

At cathode, water molecule get reduce to produce H2 gas as shown below:
2H2O+2e2OH+H2(g)

OH generated here further reacts with K+ ion present near cathode to form KOH.
2K++2OH2KOH

So, the gas generated during electrolysis of dipotassium succinate solution is ethene, CO2 and H2
Only ethyne is not liberated

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