The correct option is C H2S and SO2
MSA, metal sulfide+H2SO4→H2SB,colourless↑+MSO4C,colourless metal sulphate
K2Cr2O7+4H2SO4+3H2SB→K2SO4+Cr2(SO4)3+7H2Ogreen solution+3SD, yellow precipitate
SD+O2→SO2E↑.
SO2E+2H2SB, colourless→3SD+2H2O.
anhyd.CuSO4+5H2O→CuSO4.5H2Oblue