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Question

Which of the following gases released during the preparation of phenol from benzene diazonium chloride:

A
N2,Cl2
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B
N2,HCl
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C
NO2,Cl2
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D
N2O,Cl2
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Solution

The correct option is B N2,HCl

I) A diazonium salt is formed by treating an aromatic primary amine with nitrous acid (obtained from a mixture of NaNO2 and HCl) at low temperature of 273 K to 278 K.

II) Diazonium salts are hydrolysed to phenols treating with dilute acids which will produce nitrogen and HCl gas.

Hence option B is correct.


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