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Question

Which of the following gives positive haloform test and positive Fehling's solution test?


A
Acetone
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B
Acetaldehyde
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C
Ethanol
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D
Formaldehyde
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Solution

The correct option is D Acetaldehyde
Acetaldehyde and acetone form halofoform on heating with a halogen in the presence of a base. But acetone doesnot give a positive test with the Fehling solution, whereas acetaldehyde undergoes oxidation in the presence of Fehling solution to form the corresponding acid or salt.

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