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Optical Isomerism in Octahedral Coordination of Bidentate Ligands

Which of the ...

Question

Which of the following has an optical isomer?

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Solution

The cis form of $[C o (e n)_{2} (N H_{3})_{2}]^{3 +}$ lacks in symmetry as can be seen from the diagram, thus it is optically active.

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Optical Isomerism in Octahedral Geometry

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Optical Isomerism in Octahedral Coordination of Bidentate Ligands

Standard XIII Chemistry

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