The correct option is B Na2CO3
NaCl and KCl are salts of strong acid with strong base. They do not undergo hydrolysis in aqueous solution. Their aqueous solutions are neutral.
Sodium carbonate and bicarbonate are the salts of weak acid with strong base. Thus their solutions are basic in nature.
Now dissociation of one molecule of sodium bicarbonate gives one molecule of sodium hydroxide and one molecule of carbonic acid.
On the other hand, the dissociation of one molecule of sodium carbonate gives two molecules of sodium hydroxide and one molecule of carbonic acid.
Hence, sodium carbonate is more basic.
Na2CO3+2H2O→2NaOH+H2CO3
NaHCO3+H2O→NaOH+H2CO3