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Question

Which of the following is correct adsorption isobar for physisorption ?
Here,
(xm) is extent of adsorption per unit mass of adsorbent


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Solution

Adsorption Isobar
The variation in the amount of gas adsorbed by the adsorbent with temperature at constant pressure. It can be expressed by a curve termed as adsorption isobar.

At constant pressure P,

x is the mass of the gas adsorbed.
m is the mass of adsorbent.
(xm) is extent of adsorption per unit mass of adsorbent

For physisorption
With increase in temperature, physical adsorption decreases continuously
Hence the curve obtained is:

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