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Question

Which of the following is incorrect with respect to property indicated?

A
E.N.:F>Cl>Br
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B
E.A.:Cl>Br<F
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C
Oxidising power: F2>Cl2>Br2
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D
Bond energy: F2>Cl2>Br2
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Solution

The correct option is D Bond energy: F2>Cl2>Br2
A) E.N.:F>Cl>Br - Electonegativity decreases down the group and F is the most electronegative element.
B) E.A.:Cl>Br<F - Electron affinity of fluorine is less than that of chlorine because of small size of F atom. As a result, there is strong interelectronic repulsion in the relatively small 2p orbitals of F and thus, the incoming electron does not experience much attraction.
Oxidising power: F2>Cl2>Br2 - Flourine is stronger oxidising agent than chlorine because low bond dissociation energy of FF bond and high hydration enthalpy of F.
Bond energy F2>Cl2>Br2 is wrong because low bond dissociation energy of FF bond than ClCl.

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