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Question

Which of the following is least thermally stable?
(correct answer +1, wrong answer -0.25)

A
MgCO3
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B
CaCO3
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C
SrCO3
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D
BaCO3
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Solution

The correct option is A MgCO3
Thermal stability of group 2 carbonates increases with the increase in size of the cation. As large size anion is stablised by large size cation.
Increasing order of cation size is: Mg<Ca<Sr<Ba
So, the most stable out of these carbonates is BaCO3.

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