Among the given microorganisms, Azotobacter is an aerobic, free-living microbe that converts the atmospheric nitrogen to ammonia which is utilized by the plants.
Clostridium pasteurianum is the first known anaerobic free-living bacterium that fixing nitrogen.
A purple non sulphur anoxygenic phototrophic bacterium, Rhodopseudomonas palustris grew fixing N2 using aromatic compounds as the sole carbon source/electron donor.
Rhodospirillum rubrum is also a nitrogen fixing bacterium, i.e., it can express and regulate nitrogenase, a protein complex that can catalyse the conversion of atmospheric dinitrogen into ammonia.
Hence, the correct answer is option “A” – Azotobacter.