The correct option is D BaCl2+H2SO4→BaSO4+2HCl
(a) +2CuO+0H2→0Cu++1H2O
As oxidation number of Cu is changed from +2 to 0 and that of H is changed from 0 to +1, this is an example of redox reaction.
(b) +3Fe2O3+3+2CO→20Fe+3+4CO2
As oxidation number of Fe changes from +3 to 0 and that of C changes from +2 to +4, this is an example of redox reaction.
(c) 20K+0F2→2+1K−1F
As oxidation number of K changes from 0 to +1 and that of F changes from 0 to −1, this is an example of redox reaction.
(d) +2BaCl2+H2+6SO4→+2Ba+6SO4+2+1HCl
Oxidation number of all the elements remains unchanged. Hence, this is not an example of redox reaction.