Which of the following is optical rotatory?

C H_{3} C H C l C O O H

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C H C l C H_{2} C O O H

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C H_{2} O H C H_{2} C O O H

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C H_{2} C l C H_{2} C H_{2} C l

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Solution

The correct option is A $C H_{3} C H C l C O O H$
In the compounds the presence $- O | | C - O H$ groups makes then difficult to rotate due to this double bonded oxygen
Hence, $C l - C H_{2} - C H_{2} - C H_{2} - C l$ is rotatary.
But, optical rotatavity $\Rightarrow {C H_{3} - H^{*} | C l - C O O H}_{c h a r a l c a r b o n}$
$C H_{3} C H C l C O O H$

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