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Byju's Answer
Standard XII
Chemistry
Oxyacids of Phosphorus
Which of the ...
Question
Which of the following is the conjugate acid of
H
P
O
−
2
4
?
A
H
2
P
O
−
4
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B
P
O
−
3
4
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C
H
3
P
O
4
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D
H
3
O
+
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Solution
The correct option is
A
H
2
P
O
−
4
When a base accepts a proton, the resulting species is its conjugate acid.
Now, when
H
P
O
2
−
4
accepts a proton, it gives
H
2
P
O
−
4
.
Hence,
H
2
P
O
−
4
is the conjugate acid of
H
P
O
2
−
4
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1
Similar questions
Q.
H
3
P
O
4
+
H
2
O
⇌
H
3
O
+
+
H
2
P
O
−
4
;
p
K
1
=
2.15
H
2
P
O
−
4
+
H
2
O
⇌
H
3
O
+
+
H
P
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−
2
4
;
p
K
2
=
7.20
H
e
n
c
e
,
p
H
o
f
0.01
M
N
a
H
2
P
O
4
i
s
:
Q.
Three reactions involving
H
2
P
O
−
4
are given below.
I.
H
3
P
O
4
+
H
2
O
→
H
3
O
+
+
H
2
P
O
−
4
II.
H
2
P
O
−
4
+
H
2
O
→
H
P
O
2
−
4
+
H
3
O
+
III.
H
2
P
O
−
4
+
O
H
−
→
H
3
P
O
4
+
O
2
−
In which of the above does
H
2
P
O
−
4
act as an acid?
Q.
Consider various species generated when
H
3
P
O
4
is dissolved in water. According to the Bronsted Lowry’s Concept among these, the conjugate acid of
H
P
O
2
−
4
is :
Q.
H
2
O
+
H
3
P
O
4
⇌
H
3
O
+
+
H
2
P
O
4
−
;
p
K
1
=
2.15
H
2
O
+
H
2
P
O
−
4
⇌
H
3
O
+
+
H
P
O
2
−
4
;
p
K
2
=
7.20
Hence,
p
H
of
0.01
M
N
a
H
2
P
O
4
is:
Q.
Three reactions involving
H
2
P
O
−
4
are given below:
(i)
H
3
P
O
4
+
H
2
O
→
H
3
O
+
+
H
2
P
O
−
4
(ii)
H
2
P
O
−
4
+
H
2
O
→
H
P
O
2
−
4
+
H
3
O
+
(iii)
H
2
P
O
−
4
+
O
H
−
→
H
3
P
O
4
+
O
2
−
In which of the above reactions, does
H
2
P
O
−
4
act as an acid?
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