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B
ClCH2NH2
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C
Cl2CH−NH2
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D
CCl3−NH2
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Solution
The correct option is ACH3−NH2
As the number of chlorine atom increases, due to -I effect the basicity of amine decreases. thus CH3−NH2 is most basic amine and CCl3−NH2 is least basic amine. Hence option (a) is correct.