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Question

Which of the following is used as a differentiating solvent for acids?

A
CH3COOH
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B
H2O
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C
HClO4
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D
None of the above
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Solution

The correct option is A CH3COOH
Acetic acid CH3COOH is used as a differentiating solvent for acids due to its leveling effect. In glacial acetic acid, the acids become weak and can be differentiated due to poor proton accepting (basic) character of acetic acid (solvent).

HAAcid+CH3COOHBase(solvent)AcidCH3COOH+2+ABase

The equilibrium of the above reaction does not lie very much to the right.
Even stronger acids such as HCl, are only slightly dissociated in acetic acid. This helps in the differentiation of the acids.

Option A is correct.

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