Which of the following method is not used in the preparation of acetylene :
A
Dehydrohalogenation
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B
Dehalogenation
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C
Hydrolysis
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D
Hydrogenation
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Solution
The correct option is D Hydrogenation Alkyne can be produced by Kolbe electrolysis: acetylene can be produced by electrolysis of aq. solution of sodium/potassium maleate or fumarate. Dehydrohalogenation: Preparation of alkyne by heating ethylene bromide with alc. KOH followed by sodamide in ammonia solution. Synthesis: 2C+H2→C2H2 at high temp. and by hydrolysis.