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Question

Which of the following mixture does not obey Daltons law of partial pressures.

A
CO2 and O2 at room temperature
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B
NH3 and HCl at 00C
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C
NH3 and HCl at room temperature
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D
Excess of Cl2 and NH3
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Solution

The correct option is D NH3 and HCl at room temperature
When a mixture of NH3 and HCl react chemically with spontaneous reaction it would lead in the formation of chemical called NH4Cl.

By this the volume of the gas is automatically changed and from this reaction there is no formation of pressure. Hence the two gases do not obey Dalton's law of partial pressure

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