Which of the following mixture is non-ideal solution?

Chloroform and acetone

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Benzene and toluene

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Chlorobenzene and bromobenzene

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Bromoethane and chloroethane

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Solution

The correct option is C Chloroform and acetone
Chloroform and acetone mixture is a non-ideal solution. It shows a negative deviation from Raoult's law. It forms maximum boiling azeotrope.

Hence, option A is correct.

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