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Question

Which of the following options is/are true for XeF6?

A
It is a colourless solid that readily sublimes into intensely white vapors
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B
Hybridization of XeF6 is sp3d3
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C
It reacts with RuF5 to form [RuF4]+[XeF7]
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D
It gives XeO3 as final product on complete hydrolysis with water along with HF
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Solution

The correct options are
B Hybridization of XeF6 is sp3d3
D It gives XeO3 as final product on complete hydrolysis with water along with HF
(a) XeF6 is colourless solid which sublimes into intensely yellow vapours.

(b) According to VSEPR theory, XeF6 has 6 bond pairs and 1 lone pair so hybridises into sp3d3.

(c) XeF6+RuF5[XeF5]+[RuF6]

(d) XeF6+3H2OXeO3+6HF

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