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Question

Which of the following order is correct if we consider +I power?

Tertiary-alkyl secondary-Alkyl primary-alkyl

I II III


A

I > II > III

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B

I < II < III

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C

II > I > III

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D

III > II > I

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Solution

The correct option is D

III > II > I


We know about +I effect.

The Inductive effect is related to the ability of substituent(s) to either withdraw or donate e density to the attached C attom. Based on this ability, the substituents are classified as ewithdrawing (EWG) or edonating groups (EDG) relative to H.

EWG or e attracting groups are represented by -I and EDG or erepelling groups are represented by +I symbol.

Now,

Here, we can see that there will be a higher negative charge on carbon in case of tertiary alkyl.

Therefore, power of +I effect will be III > II > I


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