Which of the following orders is correct for heat of hydrogenation of these compounds?
A
I>II>III
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B
III>II>I
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C
II>III>I
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D
III>I>II
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Solution
The correct option is AIII>II>I Heat of hydrogenation is the measure of stability of a double bond. Smaller the numerical value of heat of hydrogenation, more stable is the double bond.
In the given compounds, considering the number of α−hydrogens, (I) is the most stable with 10α−H, followed by (III) with 4α−H. (II) is the least stable with 1−α−H. Hence, considering numerical value, the order of heat of hydrogenation is: III>II>I