Which of the following organic compound(s) undergo carbylamine reaction?

(C_{2} H_{5})_{2} N H

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C_{2} H_{5} N H_{2}

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(C_{2} H_{5})_{3} N

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(C_{2} H_{5})_{4} N^{+} I^{-}

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Solution

The correct option is B $C_{2} H_{5} N H_{2}$
Carbylamine reaction is given by only primary amine. Hence $C_{2} H_{5} N H_{2}$ gives carbylamine reaction as it is the only primary amine out of the given options.
$R - N H_{2} + C H C l_{3} + 3 K O H (a l c o h o l i c) Δ \to R - N C + 3 K C l + 3 H_{2} O$
Hence, (a),(c) and (d) do not give carbylamine reaction and are the correct options.

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