Which of the following pairs of ions is not coloured in aqueous solution?
A
Ti3+ and V3+
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B
Cu+ and Sc3+
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C
Cu2+ and Fe2+
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D
Co2+ and Ni2+
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Solution
The correct option is CCu+ and Sc3+ The ions which have unpaired electrons are found to be coloured. Those with fully-filled or empty d-orbitals are mostly colourless.
Thus, Ti3+(3d1),V3+(3d2),Cr3+(3d3),Cu2+(3d9),Fe3+(3d5) and Co2+(3d2) are all coloured due to d−d transition as they have unpaired elctrons.
Only Sc3+(3d0) and Cu+(3d10) ions are colourless since they have no unpaired electron.