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Byju's Answer
Standard XII
Chemistry
Reduction of Carboxylic Acids
Which of the ...
Question
Which of the following reaction can produce
1
o
amine as major product?
A
H
3
C
−
CH
2
−
C
≡
N
H
+
/
H
2
O
−
−−−−−−−−−−−−
→
(
Complete
hydrolysis
)
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B
H
3
C
−
C
H
2
−
O
|
|
C
−
O
H
N
3
H
−
−−
→
H
+
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C
Phthalimide
i
.
K
O
H
−
−−−−−−−−−−−−−
→
i
i
.
C
H
3
−
C
H
2
−
C
H
2
−
I
O
H
−
/
H
2
O
−
−−−−−
→
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D
CH
3
−
CH
2
−
Br
+
NH
3
(
excess
)
→
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Solution
The correct option is
D
CH
3
−
CH
2
−
Br
+
NH
3
(
excess
)
→
(a) Complete hydrolysis of nitrile gives carboxylic acid.
H
3
C
−
C
H
2
−
C
≡
N
H
+
/
H
2
O
−
−−−−
→
H
3
C
−
C
H
2
−
C
O
O
H
(b) Schmidt Reaction:
H
3
C
−
C
H
2
−
O
|
|
C
−
O
H
N
3
H
−
−−
→
H
+
H
3
C
−
C
H
2
−
N
H
2
(d) Gabriel Phthalimide Synthesis:
Phthalimide
i
.
K
O
H
−
−−−−−−−−−−−−−
→
i
i
.
C
H
3
−
C
H
2
−
C
H
2
−
I
O
H
−
/
H
2
O
−
−−−−−
→
C
H
3
−
C
H
2
−
C
H
2
−
N
H
2
(d)
CH
3
−
CH
2
−
Br
+
NH
3
(
excess
)
→
Et
−
NH
2
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