The correct option is A 2MnO2+4KOH+O2
↓
4KMnO4+2H2O
Among the given reactions,
2MNO2+4KOH+O2⟶4KMnO4+2H2O is incorrect.
This reaction gives potassium manganate as the product and not potassium permanganate.
2MNO2+4KOH+O2⟶2K2MnO4+2H2O is the correct reaction.