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Question

Which of the following reagents are used for the detection of acetate and oxalate ions respectively?

A
BaCl2 and CaCl2
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B
NaOH and BaCl2
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C
FeCl3 and CaCl2
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D
FeCl3 and NaOH
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Solution

The correct option is A FeCl3 and CaCl2
With FeCl3 solution. acetates give a deep red colouration due to the formation of ferric acetate.
3CH3COONa+FeCl3onboiling[Fe(OH)2(CH3COO)]+3NaCIBloodredcolouration
With calcium chloride solution a white crystaline precipitate of calcium oxalate from neutral solutions
is obtained, which is insoluble in dilute acetic acid and oxalic acid but soluble dilute hydrochloric
acid and in dilute nitric acid.
(C2O4)2+Ca2+CaC2O4WHITEPPT

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