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Question

Which of the following reagents are used to prepare chloroethane from ethene?

A
(i)H2/Pd, (ii)Cl2/hν
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B
(i)Cl2/hν, (i)H2/Pd
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C
CHCl3
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D
None of the above
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Solution

The correct option is A (i)H2/Pd, (ii)Cl2/hν
The correct answer is option (a). Because in the presence of H2/Pd, catalytic hydrogenation of alkene takes place which results in alkane. Free radical chlorination of alkane gives corresponding chloroalkane.

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